| ROUND | R1 | R2 | R3 | QF | SF | F |
| Season archive |
| Tuesday, 25 September 2012 | ||||||
| r3 | Queen of the South | 0-1 | Dundee United | |||
| 28 | Russell | |||||
| r3 | Celtic | 4-1 | Raith Rovers | |||
| 12 | Hooper | 28 | Walker | |||
| 37 | Hooper | |||||
| 58 | Hooper | |||||
| 60 | Hooper | |||||
| r3 | Hearts | 3-1 | Livingston | |||
| 45 | Grainger | 56 | McNulty | |||
| 70 | Žaliūkas | |||||
| 74 | Žaliūkas | |||||
| r3 | St.Johnstone | 4-1 | Queen's Park | |||
| 18 | MacLean | 30 | Keenan | |||
| 40 | MacLean | |||||
| 76 | Davidson | |||||
| 85 | Craig | |||||
| r3 | St.Mirren | 1-0 | Hamilton | |||
| 90 | Mair | |||||
| r3 | Stenhousemuir | 1-1 | Inverness CT | aet, p5-6 | ||
| 40(p) | Ferguson | 23 | McKay | |||
| Wednesday, 26 September 2012 | ||||||
| r3 | Rangers | 2-0 | Motherwell | |||
| 50 | McCulloch | |||||
| 56 | Shiels | |||||
| r3 | Dunfermline | 0-1 | Aberdeen | |||
| 90 | Vernon | |||||
| 5 | +1 | Lee McCULLOCH (Rangers) |
| 4 | Brian GRAHAM (Raith Rovers) | |
| +4 | Gary HOOPER (Celtic) | |
| +1 | Marc McNULTY (Livingston) | |
| 3 | Iain RUSSELL (Livingston, 1p) | |
| Nicky CLARK (Queen of the South) | ||
| Michael MOFFAT (Ayr United, 1p) | ||
| 2 | Andrew SHINNIE (Inverness CT) | |
| Jamie BROUGH (Queen's Park) | ||
| +1 | Dean SHIELS (Rangers) | |
| +1 | Brown FERGUSON (Stenhousemuir, 2p) | |
| Jordan MORTON (Livingston) | ||
| +2 | Marius ŽALIŪKAS (Hearts) | |
| Darren SMITH (Stenhousemuir) | ||
| Dougie HILL (Raith Rovers) | ||
| Jim LISTER (Dumbarton) | ||
| David SINCLAIR (Ayr United) | ||
| +2 | Steve MacLEAN (St.Johnstone) | |
| John GEMMELL (Stenhousemuir) | ||
| Andy BARROWMAN (Dunfermline) | ||
| Lee CURRIE (Berwick Rangers) | ||
| +1 | Scott VERNON (Aberdeen) |