| ROUND | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 |
| 20 | 21 | 22 | 23 | 24 | 25 | 26 | 27 | 28 | 29 | 30 | 31 | 32 | 33 | 34 | 35 | 36 | 37 | 38 |
| Season archive |
| Games | Goals | H | D | A | ||||
| 70 | 191 | 2.72 | 37 | 52.86% | 16 | 22.86% | 17 | 24.29% |
| 1999/00 | Overall | Home | Away | |||||||||||||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | P | W | D | L | F | A | P | W | D | L | F | A | ||||
| 1 | Barcelona | 7 | 5 | 1 | 1 | 16 | 6 | +10 | 16 | XWWL | 4 | 3 | 1 | 0 | 11 | 3 | 3 | 2 | 0 | 1 | 5 | 3 | ||
| 2 | Rayo Vallecano | 7 | 5 | 1 | 1 | 10 | 5 | +5 | 16 | WXLW | 4 | 3 | 0 | 1 | 6 | 4 | 3 | 2 | 1 | 0 | 4 | 1 | ||
| 3 | Celta Vigo | 7 | 5 | 0 | 2 | 9 | 5 | +4 | 15 | WWWL | 4 | 3 | 0 | 1 | 5 | 3 | 3 | 2 | 0 | 1 | 4 | 2 | ||
| 4 | 2 | Deportivo | 7 | 3 | 3 | 1 | 12 | 8 | +4 | 12 | XWLX | 3 | 2 | 0 | 1 | 6 | 3 | 4 | 1 | 3 | 0 | 6 | 5 | |
| 5 | 1 | Espanyol | 7 | 4 | 0 | 3 | 11 | 11 | +0 | 12 | LWWW | 3 | 3 | 0 | 0 | 8 | 4 | 4 | 1 | 0 | 3 | 3 | 7 | |
| 6 | 1 | Zaragoza | 7 | 3 | 2 | 2 | 9 | 5 | +4 | 11 | LWWX | 3 | 2 | 1 | 0 | 7 | 1 | 4 | 1 | 1 | 2 | 2 | 4 | |
| 7 | 4 | Racing Santander | 7 | 3 | 2 | 2 | 13 | 11 | +2 | 11 | WXLX | 3 | 0 | 2 | 1 | 4 | 5 | 4 | 3 | 0 | 1 | 9 | 6 | |
| 8 | Real Madrid | 7 | 2 | 4 | 1 | 14 | 11 | +3 | 10 | XLXX | 3 | 1 | 1 | 1 | 7 | 5 | 4 | 1 | 3 | 0 | 7 | 6 | ||
| 9 | 2 | Alavés | 7 | 3 | 1 | 3 | 7 | 8 | -1 | 10 | LOLW | 3 | 2 | 1 | 0 | 4 | 2 | 4 | 1 | 0 | 3 | 3 | 6 | |
| 10 | 3 | Valladolid | 7 | 2 | 2 | 3 | 6 | 8 | -2 | 8 | XLOW | 3 | 2 | 0 | 1 | 5 | 4 | 4 | 0 | 2 | 2 | 1 | 4 | |
| 11 | 1 | Numancia | 7 | 2 | 2 | 3 | 6 | 13 | -7 | 8 | LXWX | 3 | 1 | 2 | 0 | 3 | 2 | 4 | 1 | 0 | 3 | 3 | 11 | |
| 12 | 5 | Athletic Bilbao | 7 | 2 | 2 | 3 | 11 | 12 | -1 | 8 | WLLX | 3 | 1 | 1 | 1 | 5 | 5 | 4 | 1 | 1 | 2 | 6 | 7 | |
| 13 | 4 | Málaga | 7 | 2 | 2 | 3 | 12 | 12 | +0 | 8 | LXXL | 4 | 2 | 1 | 1 | 8 | 5 | 3 | 0 | 1 | 2 | 4 | 7 | |
| 14 | 2 | Real Sociedad | 7 | 2 | 1 | 4 | 11 | 15 | -4 | 7 | LLLW | 4 | 2 | 0 | 2 | 8 | 9 | 3 | 0 | 1 | 2 | 3 | 6 | |
| 15 | 1 | Real Betis | 7 | 2 | 1 | 4 | 3 | 11 | -8 | 7 | LWLW | 3 | 2 | 1 | 0 | 2 | 0 | 4 | 0 | 0 | 4 | 1 | 11 | |
| 16 | 2 | Sevilla | 7 | 1 | 4 | 2 | 9 | 8 | +1 | 7 | WOLX | 4 | 1 | 2 | 1 | 6 | 4 | 3 | 0 | 2 | 1 | 3 | 4 | |
| 17 | 2 | Mallorca | 7 | 2 | 1 | 4 | 10 | 10 | +0 | 7 | XLWL | 4 | 2 | 1 | 1 | 8 | 5 | 3 | 0 | 0 | 3 | 2 | 5 | |
| 18 | 1 | Valencia | 7 | 2 | 1 | 4 | 10 | 10 | +0 | 7 | WWOL | 4 | 1 | 1 | 2 | 5 | 4 | 3 | 1 | 0 | 2 | 5 | 6 | |
| 19 | 3 | Real Oviedo | 7 | 2 | 1 | 4 | 5 | 10 | -5 | 7 | XLWL | 4 | 2 | 1 | 1 | 4 | 3 | 3 | 0 | 0 | 3 | 1 | 7 | |
| 20 | Atlético Madrid | 7 | 2 | 1 | 4 | 7 | 12 | -5 | 7 | WLWX | 4 | 2 | 0 | 2 | 4 | 4 | 3 | 0 | 1 | 2 | 3 | 8 | ||
| 9 | +4 | SALVA (Racing Santander, 5p) |
| 6 | +2 | CATANHA (Málaga, 1p) |
| 5 | DANI (Barcelona) | |
| +1 | Savo MILOŠEVIĆ (Zaragoza) | |
| +1 | RIVALDO Vitor (Barcelona) | |
| 4 | Roy MAKAAY (Deportivo) | |
| Miguel BENÍTEZ (Espanyol) | ||
| +1 | Joseba ETXEBERRIA (Athletic Bilbao) | |
| +2 | RAÚL González (Real Madrid) | |
| +1 | Jimmy HASSELBAINK (Atlético Madrid) | |
| 3 | CARLITOS (Mallorca) | |
| Gaizka MENDIETA (Valencia, 3p) | ||
| +2 | PAULETA (Deportivo) | |
| +1 | Victor BONILLA (Real Sociedad) | |
| DIEGO TRISTÁN Herrera (Mallorca, 1p) | ||
| +1 | Julio DELY VALDÉS (Real Oviedo) | |
| Fernando MORIENTES (Real Madrid) | ||
| DJALMINHA (Deportivo, 1p) | ||
| Valeri KARPIN (Celta Vigo, 1p) | ||
| Vassilis TSIARTAS (Sevilla) | ||
| +1 | JUAN CARLOS Gómez (Sevilla) | |
| VÍCTOR Manuel (Valladolid) |
| Monday, 11 October 1999 | |||||
| 7 | Atlético Madrid | 1-0 | Alavés | ||
| 76 | Hasselbaink | ||||
| Tuesday, 12 October 1999 | |||||
| 7 | Sevilla | 3-0 | Real Betis | ||
| 1 | Quevedo | ||||
| 74 | Juan Carlos | ||||
| 90 | Loren | ||||
| 7 | Mallorca | 2-2 | Deportivo | ||
| 80 | Quinteros | 48 | Pauleta | ||
| 90(p) | Stankovic | 57 | Pauleta | ||
| 7 | Málaga | 3-4 | Athletic Bilbao | ||
| 27 | Edgar | 21 | Alkorta | ||
| 47 | Catanha | 73 | Lacruz | ||
| 61(p) | Catanha | 87 | Lacruz | ||
| 90 | Etxeberria | ||||
| Wednesday, 13 October 1999 | |||||
| 7 | Real Oviedo | 1-1 | Valladolid | ||
| 16 | Dely Valdés | 69 | Rodrigo Fabri | ||
| 7 | Valencia | 4-0 | Numancia | ||
| 30 | Ilie | ||||
| 52 | Ilie | ||||
| 69 | Farinós | ||||
| 90 | Óscar | ||||
| 7 | Barcelona | 2-2 | Real Madrid | ||
| 29 | Rivaldo | 27 | Raúl | ||
| 90 | Figo | 85 | Raúl | ||
| 7 | Real Sociedad | 2-5 | Racing Santander | ||
| 3 | Bonilla | 46 | Munitis | ||
| 84 | Antiá | 62 | Salva | ||
| 67 | Salva | ||||
| 71 | Salva | ||||
| 85 | Salva | ||||
| 7 | Celta Vigo | 2-1 | Zaragoza | ||
| 36 | Cáceres | 27 | Milošević | ||
| 54 | Mostovoi | ||||
| 7 | Rayo Vallecano | 2-1 | Espanyol | ||
| 47 | Hernández | 88 | Velamazán | ||
| 82 | Canabal | ||||